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From
•>>February 2007
Frank T. Edelmann answers a
few questions about this month's emerging research front in
the field of Chemistry.
Chemistry
Article: Synthesis and structural chemistry of non-cyclopentadienyl organolanthanide complexes
Authors: Edelmann,
FT;Freckmann, DMM;Schumann, H
Journal: CHEM REV, 102 (6): 1851-1896, JUN 2002
Addresses:
Otto Von Guericke Univ, Inst Chem, Univ Pl 2, Magdeburg, Germany.
Otto Von Guericke Univ, Inst Chem, Magdeburg, Germany.
Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany.
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Why do you think your paper is
highly cited?
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“...but besides Europe the majority of exciting results originates from the United States and China.”
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Such review articles are often highly cited, provided that
they cover hot topics of significant current interest.
Organometallic compounds of the rare earth elements offer very
promising applications in the fields of catalysis and
materials science. Thus the article was most likely cited not
only by chemists but also by researchers working in these
particular areas.
Does it describe a new discovery or a new methodology
that’s useful to others?
It provides a comprehensive account of a rapidly developing
field and summarizes new discoveries made by research groups
all over the world. Of course, our own work is also included.
Besides Europe, the majority of exciting results have
originated from the United States and China.
Could you summarize the significance of your paper in
layman’s terms?
The lanthanides form the largest group of naturally
occurring elements in the Periodic Table. Although not always
obvious to the general public, lanthanide compounds find
numerous important applications such as in lasers (neodymium),
and as phosphors in color TV tubes (europium) or MRI
scans (gadolinium). The subject area, organolanthanide
complexes, has its major impact in the field of catalysis,
e.g., in the catalytic manufacture of various important
industrial polymers.
How did you become involved in this research?
We became interested in the organometallic chemistry of the
lanthanides—or rare earths, as they are often termed—almost
20 years ago. One of the co-authors of this review, Prof. Dr.
Herbert Schumann of the Technische Universität Berlin, is
perhaps the pioneer researcher in this area, as someone who
stimulated the work of numerous other research groups.
We and others observed that this particular group of
elements displays unique reactivities unprecedented for any
other metals. In part, we initiated the new direction
summarized in this review article. The compounds compiled in
this review offer a tremendous variety of possible structures
and applications.
Are there any social or political implications for your
research?
Unlike many heavy metals, the lanthanide elements are
generally non-toxic. As a long-term consideration, the
development of organolanthanide catalysts, e.g., for the
industrial production of polymers, is an important
contribution to a true "green chemistry."
Dr. Frank T. Edelmann
Professor of Chemistry
Otto-von-Guericke University
Magdeburg, Germany
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