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ESI Special Topics, March 2003
Citing URL: http://www.esi-topics.com/fmf/2003/march03-BretJackson.html

From •>>March 2003

Professor Bret E. Jackson answers a few questions about this month's fast moving front in the field of Computer Science.

Field: Computer Science
Title: "Eley-Rideal reactions between H atoms on metal and graphite surfaces: The variation of reactivity with substrat"
Authors: Jackson, B;Lemoine, D
Journal: J CHEM PHYS, 114: (1) 474-482 JAN 1 2001
Addresses:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA.
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA.
Univ Lille 1, Ctr Etud & Rech Lasers & Applicat, UMR CNRS 8523, Lab Phys Lasers Atomes & Mol, F-59655 Villeneuve Dascq, France.


ST:  Why do you think your paper is highly cited?

An Eley-Rideal reaction takes place when a gas-phase particle reacts with another particle adsorbed onto a substrate. Eley-Rideal reactivity varies widely from system to system.  For example, the probability for H atom recombination is small on metals, while it is large on graphite.  Our paper is highly cited because it successfully explains this variation in reactivity in terms of a few simple ideas. In addition, H atom recombination on the graphitic surfaces of interstellar dust grains is currently a "hot" topic in astrophysics.

ST:  Does it describe a new discovery or new methodology that's useful to others?

Eley-Rideal reactions have only recently been observed in the laboratory, and our work helps to explain the experimental observations, and understand the basic mechanisms involved.

ST:  How did you become involved in this research?

During a visit, a Swedish colleague showed me two Phys. Rev. Letters purporting to have discovered the first experimental evidence for Eley-Rideal reactions (H atom recombination on a metal wall).  He and I decided to simulate the reaction just to see what was going on.

ST:  Could you summarize the significance of your paper in layman's terms?

The vast amounts of molecular hydrogen existing in interstellar space are believed to have formed when H atoms collide and combine with other H atoms adsorbed onto dust grains.

We have demonstrated that this mechanism for molecular hydrogen formation is highly efficient when the interaction of the H atoms with the substrate (the dust grain, in this case) is relatively weak. Thus, molecular hydrogen formation on graphitic dust grains, where the H-graphite attraction is weak, should be highly probable.End

Professor Bret E. Jackson
University of Massachusetts,
Department of Chemistry,
Amherst, MA
USA

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ESI Special Topics, March 2003
Citing URL: http://www.esi-topics.com/fmf/2003/march03-BretJackson.html

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