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From
•>>March 2003
Professor Bret E. Jackson answers
a few questions about this month's fast moving front in the
field of Computer Science.
Field:
Computer Science
Title: "Eley-Rideal reactions between H atoms on metal and graphite surfaces: The variation of reactivity with substrat"
Authors: Jackson,
B;Lemoine, D
Journal: J CHEM PHYS, 114: (1) 474-482 JAN 1 2001
Addresses:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA.
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA.
Univ Lille 1, Ctr Etud & Rech Lasers & Applicat, UMR CNRS 8523, Lab Phys Lasers Atomes & Mol, F-59655 Villeneuve
Dascq, France. |
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Why
do you think your paper is highly cited?
An Eley-Rideal reaction takes
place when a gas-phase particle reacts with another particle
adsorbed onto a substrate. Eley-Rideal reactivity varies widely
from system to system. For example, the probability for H
atom recombination is small on metals, while it is large on
graphite. Our paper is highly cited because it
successfully explains this variation in
reactivity in terms of a few
simple ideas. In
addition, H atom recombination on the graphitic surfaces of
interstellar dust grains is currently a "hot" topic in
astrophysics.
Does
it describe a new discovery or new methodology that's useful to
others?
Eley-Rideal reactions have only
recently been observed in the laboratory, and our work helps to
explain the experimental observations, and understand the basic
mechanisms involved.
How
did you become involved in this research?
During a visit, a Swedish
colleague showed me two Phys. Rev. Letters purporting to
have discovered the first experimental evidence for Eley-Rideal
reactions (H atom recombination on a metal wall). He and I
decided to simulate the reaction just to see what was going on.
Could
you summarize the significance of your paper in layman's terms?
The vast amounts of molecular
hydrogen existing in interstellar space are believed to have
formed when H atoms collide and combine with other H atoms
adsorbed onto dust grains.
We have demonstrated that this mechanism for molecular
hydrogen formation is highly efficient when the interaction of
the H atoms with the substrate (the dust grain, in this case) is
relatively weak.
Thus,
molecular hydrogen formation on graphitic dust grains, where the
H-graphite attraction is weak, should be highly probable.
Professor Bret E. Jackson
University of Massachusetts,
Department of Chemistry,
Amherst, MA
USA
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