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New Hot Paper Comments

By Laurence S. Rothman

ESI Special Topics, May 2006
Citing URL - http://www.esi-topics.com/nhp/2006/may-06-LaurenceSRothman.html

Laurence S. Rothman answers a few questions about this month's new hot paper in the field of Engineering.

From •>>May 2006

Field: Engineering
Article Title: The HITRAN 2004 molecular spectroscopic database
Authors: Rothman, LS;Jacquemart, D;Barbe, A;Benner, DC;Birk, M;Brown, LR;Carleer, MR;Chackerian, C;Chance, K;Coudert, LH;Dana, V;Devi, VM;Flaud, JM;Gamache, RR;Goldman, A;Hartmann, JM;Jucks, KW;Maki, AG;Mandin, JY;Massie, ST;Orphal, J;Perrin, A;Rinsland, CP;Smith, MAH;Tennyson, J;Tolchenov, RN;Toth, RA;Vander Auwera, J;Varanasi, P;Wagner, G
Journal: J QUANT SPECTROSC RADIAT
Volume: 96
Issue: 2
Page: 139-204
Year: DEC 1 2005
* Harvard Smithsonian Ctr Astrophys, Atom & Mol Phys Div, 60 Garden St, Cambridge, MA 02138 USA.
* Harvard Smithsonian Ctr Astrophys, Atom & Mol Phys Div, Cambridge, MA 02138 USA.
* Univ Reims, Grp Spectrometrie Mol & Atmospher, F-51062 Reims, France.
* Coll William & Mary, Dept Phys, Williamsburg, VA 23187 USA.
* DLR, Remote Sensing Technol Inst, Wessling, Germany.
* CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA.
* Free Univ Brussels, Serv Chim Quant & Photophys, B-1050 Brussels, Belgium.
* NASA, Ames Res Ctr, Moffett Field, CA 94035 USA.
* Univ Paris 11, Photophys Mol Lab, F-91405 Orsay, France.
* Univ Paris 06, Lab Phys Mol & Applicat, F-75252 Paris, France.
* Univ Mass Lowell, Dept Environm Earth & Atmospher Sci, Lowell, MA 01854 USA.
* Univ Denver, Dept Phys, Denver, CO 80208 USA.
* Harvard Smithsonian Ctr Astrophys, Opt & Infrared Astron Div, Cambridge, MA 02138 USA.
* Natl Ctr Atmospher Res, Boulder, CO 80307 USA.
* NASA, Langley Res Ctr, Hampton, VA 23681 USA.
* Univ London Univ Coll, Dept Phys & Astron, London WC1E 6BT, England.
* SUNY Stony Brook, Stony Brook, NY 11794 USA.

ST:  Why do you think your paper is highly cited?

The HITRAN spectroscopic database which I manage provides input for a vast array of applications in the scientific, industrial, and academic community. I currently maintain a list of about 5,500 active users throughout the world.

ST:  Does it describe a new discovery or a new methodology that's useful to others?


“Enhanced data entered into the archive have been acquired from recent experiments and theoretical calculations...”

HITRAN is an archive of spectroscopic data that has been cast into a convenient format for general use. It is continuously enhanced with new data acquired from recent experiments and theoretical calculations, and they have been validated for inclusion into the database.

ST:  Could you summarize the significance of your paper in layman's terms?

Matter in the gas phase interacts with electromagnetic radiation such as visible light, infrared, microwave, and ultraviolet. Due to the physics of quantum mechanics, the molecules absorb the radiation at discrete frequencies. This so-called spectrum resembles a set of uneven picket fences, and is unique to each molecule.

In essence, each species has its own special "fingerprint." Owing to the high sensitivity and resolution of modern instruments, one is able to extract a great deal of information about the scene if one has the spectroscopic "template" of the species in question.

The HITRAN database provides such an archive for many gases, and enables scientists to obtain information such as the quantity of gas in the path, the temperature of the gas, or the pressure, without physically interfering with the gas being probed. HITRAN acts as an analogy to the human genome project.

ST:  How did you become involved in this research, and were any problems encountered along the way?

My doctoral studies were in obtaining highly accurate energy levels and intensities of molecules like water vapor, ozone, and sulfur dioxide, by using theoretical methods. At about that time, a confluence of technologies became available: computational power, sensitive detectors, and new high-resolution spectrometers. These technologies led to the need for a machine-readable compilation of spectroscopic parameters.

The ensuing problems have been in keeping up with the demands of observations, particularly the improved satellite remote-sensing experiments, which are requiring very high accuracy of the spectroscopic parameters. In addition, the increased sophistication of remote-sensing retrieval algorithms has made necessary the inclusion of more subtle physical effects in the database. Funding the effort of such a scale has also been a continual challenge.

ST:  What are the social or political implications of your research?

HITRAN is unique in many ways. It includes information about a wide array of atmospheric molecules and is invaluable in many applications. A stringent testing of the data, before inclusion into the archive, makes it a worldwide standard for much smaller and highly specialized databases. It is also an international effort, involving scientific research from many well-established research laboratories.

There are many implications of the research to which HITRAN is applied. It is used extensively for monitoring of the terrestrial atmosphere, especially global warming, ozone depletion, and trace-gas (atmospheric pollutant) change. These have an effect on government policies.

The commercial uses, such as detecting pollution, monitoring industrial processes and effluents, and surveillance are very extensive.

The database has many military applications, especially in the detection of plumes seen through the atmosphere in order to provide advanced warnings on the launching of missiles. The HITRAN database also has applications with regard to astronomy and astrophysics. Examples are provided in a recent session on "Spectroscopy and Radiative Transfer in Planetary Atmospheres" that was held at the European Geosciences Union conference in Vienna. Indeed, the database applications for extra-solar planets, stars, and eventually astrobiology, are very exciting prospects for the future.

Dr. Laurence S. Rothman
Physicist
Harvard-Smithsonian Center for Astrophysics
Atomic and Molecular Physics Division
Cambridge, MA, USA


Read an in-cites.com interview with Laurence S. Rothman.

ESI Special Topics, May 2006
Citing URL - http://www.esi-topics.com/nhp/2006/may-06-LaurenceSRothman.html

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